The most sterically crowded alkanes prepared so far are 1 19 and 2 20, with C–C bonds of up to 1.65 Å. They are considered thermally labile, as expressed in the half-life of 1 h for 2 at 167 °C. Even ...
Methanogenesis is an ancient metabolism of key ecological relevance, with direct impact on the evolution of Earth’s climate. Recent results suggest that the diversity of methane metabolisms and their ...
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