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A pink solid has the formula CoCl2·NH3·H2O. A solution of this salt is also pink and rapidly gives 3 mol AgCl on titration with silver nitrate solution.When the pink solid is heated, it loses 1 mol H2O to give a purple solid with the same ratio of NH3:Cl:Co. The purple solid, on dissolution and titration with AgNO3, releases one of its chlorides rapidly. Deduce the structural formula of the two octahedral complexes [Co(NH3)4Cl2] and [Co(NH3)5(H2O)]Cl2.
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Oct 18, 2021
numerade.com
SOLVED:Prepare a spreadsheet to plot the titration curve of 100  mL 0.1 M chloride titrated with 0.1 M silver nitrate (Figure 11.1 ). See your CD for a suggested setup. Use the spreadsheet to change the concentrations of chloride and silver (e.g., 0.2 M each, 0.05 M each), and notice how the titration curve changes. Note that there is a limit to how low the concentrations can go in these calculated plots because eventually the solubility of the AgCl at 99.9 and 100.1  mL titrant becomes apprecia
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4 months ago
numerade.com
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